Dean made a great observation about hue shifts through the face. Due to the way blood vessels are grouped, colours are different in various areas. The bottom jaw and lip area takes a slightly bluish tinge, the nose and cheekbones a pinky red tone, and the forehead (being mostly bone) is slightly yellower.
Here’s a quick paintover to illustrate my point. This is one of my older characters. On the left, she’s been painted in a standard way with a skin shader. On the right, I’ve overlaid a slight hue shift through her face, which instantly gives a lot more life and volume to it. It’s probably a bit strong but I wanted to make it easier to see.
Try it out with your own work and see how you go!
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